Soaking up the Sunshine

Soaking up the Sunshine

I’m heading to the beach for Labor Day but I don’t want to get sunburnt so I did some research into sunscreen options. I had lots of questions, but my main one was what makes sunscreen effective against the UV rays? It’s actually the active ingredients in sunscreen that protect from UV rays and depending what type of sunscreen the active ingredients are responsible for absorbing the UV photons or reflecting them away from the body.

Through my research I also learned:

  1. There are two main groups of UV rays to be mindful of: UVA and UVB. 
  2. SPF (Sun protection factor) is telling how well the sunscreen protects your skin from UVB radiation. The higher the SPF the more UVB rays blocked.  
  3. Broad spectrum coverage- SPF only refers to the UVB rays being blocked so finding a sunscreen that says broad spectrum coverage will also provide protection from UVA rays.  

I remember when I was growing up my mother would always make me reapply sunscreen while we were at the beach, but I had applied some that morning and didn’t think I needed it. I learned my lesson and was very sunburnt, so this made me question how fast the active ingredients actually degrade. So, I set up an experiment where I put sunscreen into plastic bags, spread the sunscreen very thin as if it was being applied to skin and then set the bags out on the sidewalk for preset amounts of time.  

At the end of the day, I weighed about 200mg of sunscreen into a tube and dissolved in methanol. I did a 20x dilution and filtered the samples into vials. I ran the following method to compare the sun-treated samples to some fresh from the bottle.

Sunscreen-Stages

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Banana boat listed 4 active ingredients, and Coppertone listed 2 active ingredients. Sunscreen that has not been exposed to the UV rays showed matching numbers of peaks to the active ingredients. We did not specifically confirm the identity of the peaks and intended for this study to be qualitative. After 2 and 6 hours in the sun, Banana Boat showed slightly lower peak heights when compared to the no sun exposure control. After sun exposure of Coppertone, a third peak was seen splitting off of the first one. This is suspected to be a degradation peak of one of the active ingredients.

The changes in peak heights were not as drastic as I expected at the 2- or 6-hour point, but they do show degradation in the sunscreen after sun exposure. I’ll definitely be packing lots of sunscreen for vacation!

Methanol Blank

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